Answer: A. NCERT states: "One mole contains exactly 6.02214076×10²³ elementary entities. This number is the fixed numerical value of the Avogadro constant." Just as the second fixes the caesium frequency and the kilogram fixes the Planck constant, the mole fixes the Avogadro constant — each of the seven base units is defined this same way, by pinning down one constant's numerical value (NCERT Class 11 Physics Chapter 1, page 2).
Why B is wrong: B is wrong because none of the seven modern SI base units — including the mole — is defined via a physical prototype any longer. A reference-artifact definition describes the OLD (pre-2019) kilogram standard, not the current mole definition, which fixes the Avogadro constant instead. (trap: confusing the mole with the historical prototype-based approach to the kilogram)
Why C is wrong: C is wrong because each base unit's modern definition fixes its OWN constant independently — the mole's definition fixes the Avogadro constant on its own, without needing the Planck constant (used for the kilogram) to appear in the same defining statement. (trap: assuming the constants are chained together in one combined definition)
Why D is wrong: D is wrong because amount of substance is precisely one of the seven SI base quantities, measured independently by counting elementary entities (in units of mole) — NCERT lists it alongside length, mass, and the others as a base quantity. (trap: assuming only mechanical quantities like mass or length can be 'base' quantities)