Latent heat
Q = m L during phase transition at constant T. L_fusion (water): 3.34 × 10⁵ J/kg. L_vaporisation (water): 2.26 × 10⁶ J/kg. Latent heat is absorbed/released without temperature change.
-- NCERT, p. 7A common confusion in NEET problems on change of state: treating latent heat as "extra temperature" instead of recognising that temperature stays constant during a phase transition. The heat you supply at the melting or boiling point does not raise temperature — it breaks intermolecular bonds.
What latent heat means. When a substance reaches its melting point (or boiling point), additional heat goes entirely into changing the phase. The formula is Q = mL, where L is the specific latent heat — either L_fusion (solid → liquid) or L_vaporisation (liquid → gas). For water: L_fusion ≈ 3.34 × 10⁵ J/kg; L_vaporisation ≈ 2.26 × 10⁶ J/kg (NCERT Class 11 Physics, Chapter 11, page 7).
The flat region on the heating curve. Plot temperature vs heat supplied for ice → water → steam. You get two flat plateaus — one at 0 °C (fusion) and one at 100 °C (vaporisation). During each plateau, Q = mL applies; between plateaus, Q = mcΔT applies.
Where NEET problems test you. A typical question gives you a mass of ice at some sub-zero temperature and asks for the total heat to convert it fully to steam at 100 °C. You must chain three or more stages: (1) heat ice from initial temperature to 0 °C using Q = mcΔT with c_ice, (2) melt ice at 0 °C using Q = mL_fusion, (3) heat water from 0 °C to 100 °C using Q = mcΔT with c_water, (4) vaporise water using Q = mL_vaporisation. Missing any stage — or applying the wrong specific heat for the wrong phase — costs you the mark.
Watch out: L_vaporisation is roughly 6.8 times L_fusion for water. If your answer for total heat is dominated by the fusion step rather than the vaporisation step, re-check — you may have swapped the two values.
Select an option to see the explanation. Wrong answers show why your choice was tempting — and name the exact trap it exploits.
During the melting of ice at 0 °C and 1 atm pressure, the temperature of the ice-water mixture:
The SI unit of specific latent heat is:
For water at standard pressure, the specific latent heat of vaporisation is approximately:
How much heat is required to melt 0.50 kg of ice at 0 °C completely into water at 0 °C? (L_fusion = 3.34 × 10⁵ J/kg)
200 g of ice at 0 °C is mixed with 200 g of water at 80 °C in a thermally insulated container. What is the final temperature of the mixture? (L_fusion = 3.34 × 10⁵ J/kg, c_water = 4.18 × 10³ J/(kg·K))
On a heating curve (temperature vs heat supplied) for a pure substance, the slope of the curve during a phase change is:
Calculate the total heat required to convert 100 g of ice at −10 °C to steam at 100 °C. (c_ice = 2.09 × 10³ J/(kg·K), L_fusion = 3.34 × 10⁵ J/kg, c_water = 4.18 × 10³ J/(kg·K), L_vaporisation = 2.26 × 10⁶ J/kg)
A 50 g copper calorimeter (c_copper = 390 J/(kg·K)) contains 100 g of water at 30 °C. A 20 g piece of ice at 0 °C is dropped in. Find the final equilibrium temperature. (L_fusion = 3.34 × 10⁵ J/kg, c_water = 4.18 × 10³ J/(kg·K))
Given
- Mass: m = 50 g = 0.050 kg - Initial temperature: T_i = −20 °C - Final temperature: T_f = 40 °C - c_ice = 2.09 × 10³ J/(kg·K) - L_fusion = 3.34 × 10⁵ J/kg - c_water = 4.18 × 10³ J/(kg·K)
Required
Total heat Q_total to go from ice at −20 °C to water at 40 °C.
Concept
Three stages: (1) heat ice from −20 °C to 0 °C, (2) melt ice at 0 °C, (3) heat water from 0 °C to 40 °C. Each stage uses a different formula or different value of c.
Formulas
- Stage 1: Q₁ = m × c_ice × ΔT₁ - Stage 2: Q₂ = m × L_fusion - Stage 3: Q₃ = m × c_water × ΔT₃
Substitution
- Q₁ = 0.050 × 2090 × 20 = ? - Q₂ = 0.050 × 3.34 × 10⁵ = ? - Q₃ = 0.050 × 4180 × 40 = ?
Calculation
- Q₁ = 0.050 × 2090 × 20 = 2,090 J - Q₂ = 0.050 × 334,000 = 16,700 J - Q₃ = 0.050 × 4180 × 40 = 8,360 J - Q_total = 2,090 + 16,700 + 8,360 = 27,150 J Note on exact values: the temperature intervals (20 K and 40 K) are exact by problem definition and do not limit significant figures.
Final answer
Q_total ≈ 2.72 × 10⁴ J The dominant contribution is the melting step (16,700 J, about 61% of the total), followed by heating water (8,360 J, about 31%), then heating ice (2,090 J, about 8%). If a problem involves vaporisation as well, expect the vaporisation term to dominate overwhelmingly.
Common trap
Forgetting to use c_ice for the sub-zero heating stage and instead using c_water throughout. Since c_ice ≈ 0.50 × c_water, this error overestimates Q₁ by a factor of 2. Always check: which phase is the substance in during each stage?
Similar NEET-style question
A 200 g block of ice at −15 °C is placed in an insulated container with 300 g of water at 50 °C. Determine the final equilibrium temperature and state of the mixture. (Same constants as above.) *Approach: calculate heat available from water cooling to 0 °C, compare with heat needed to warm ice to 0 °C + melt it. If surplus heat remains, all ice melts and final T > 0 °C. If deficit, some ice remains at 0 °C.* ---
Q = m L during phase transition at constant T. L_fusion (water): 3.34 × 10⁵ J/kg. L_vaporisation (water): 2.26 × 10⁶ J/kg. Latent heat is absorbed/released without temperature change.
-- NCERT, p. 7Conservation of energy along a streamline of incompressible non-viscous flow.
| Symbol | Quantity | SI Unit |
|---|---|---|
| P | pressure | Pa |
| rho | density | kg/m^3 |
| v | speed | m/s |
| g | gravity | m/s^2 |
| h | height | m |
Resistance of a material to uniform compression. Inverse: compressibility.
| Symbol | Quantity | SI Unit |
|---|---|---|
| K | bulk modulus | Pa |
| V | volume | m^3 |
| P | pressure | Pa |
Height a liquid rises (or falls) in a capillary tube. cos(theta) > 0: rises (wetting); < 0: depresses.
| Symbol | Quantity | SI Unit |
|---|---|---|
| h | capillary height | m |
| T | surface tension | N/m |
| theta | contact angle | rad |
| rho | density | kg/m^3 |
| r | tube radius | m |
Pressure at depth h below free surface of fluid of density rho.
| Symbol | Quantity | SI Unit |
|---|---|---|
| P | total pressure | Pa |
| P0 | atmospheric/surface pressure | Pa |
| rho | density | kg/m^3 |
| h | depth | m |
Heat absorbed/released during phase change at constant T. L_fusion or L_vaporisation.
| Symbol | Quantity | SI Unit |
|---|---|---|
| Q | heat | J |
| m | mass | kg |
| L | latent heat | J/kg |
Heat required to raise mass m by temperature Delta_T. Specific heat c is material property.
| Symbol | Quantity | SI Unit |
|---|---|---|
| Q | heat | J |
| m | mass | kg |
| c | specific heat | J/kg/K |
| Delta_T | temp change | K |
Radiation power from a body. Black body epsilon=1; net to surroundings P = sigma*epsilon*A*(T^4 - T_s^4).
| Symbol | Quantity | SI Unit |
|---|---|---|
| sigma | Stefan-Boltzmann = 5.67e-8 | W/m^2/K^4 |
| epsilon | emissivity (0-1) | - |
| A | surface area | m^2 |
| T | absolute temp | K |
Drag force on a sphere of radius r moving with velocity v through viscous fluid (low Reynolds number).
| Symbol | Quantity | SI Unit |
|---|---|---|
| F | drag force | N |
| eta | viscosity | Pa*s |
| r | sphere radius | m |
| v | velocity | m/s |
Excess internal pressure due to surface tension. Bubble has 2 surfaces, hence factor 4.
| Symbol | Quantity | SI Unit |
|---|---|---|
| Delta_P | excess pressure | Pa |
| T | surface tension | N/m |
| r | radius | m |
Constant velocity reached when net force is zero (gravity balanced by buoyancy + viscous drag).
| Symbol | Quantity | SI Unit |
|---|---|---|
| v_t | terminal velocity | m/s |
| r | sphere radius | m |
| rho_s | sphere density | kg/m^3 |
| rho_f | fluid density | kg/m^3 |
| eta | viscosity | Pa*s |
Fractional change in length, area, volume per degree temperature change.
| Symbol | Quantity | SI Unit |
|---|---|---|
| alpha | linear coefficient | 1/K |
| beta | volume coefficient | 1/K |
| Delta_T | temperature change | K |
Ratio of longitudinal stress to longitudinal strain in a stretched wire/rod within elastic limit.
| Symbol | Quantity | SI Unit |
|---|---|---|
| Y | Young's modulus | Pa |
| F | applied force | N |
| A | cross-section area | m^2 |
| L | original length | m |
| Delta_L | extension | m |
These are the exact patterns that cause wrong answers in NEET. Each trap includes when it triggers and how to avoid it.
Category: Similar Terms
Student uses 2T/r for soap bubble (drop formula). Bubble has 2 surfaces → 4T/r.
Question mentions soap bubble OR liquid drop OR air bubble in liquid.
Drop in air: 1 surface → 2T/r. Soap bubble in air: 2 surfaces → 4T/r. Air bubble in liquid: 1 surface → 2T/r.
Category: Similar Terms
Student uses Y formula when problem is about volumetric compression (use K) or vice versa.
Problem describes longitudinal stretching (use Y), volumetric pressure (use K), or shear (use G).
Y: longitudinal stress/strain. K: volumetric. G: shear. Match modulus to deformation type.
Root cause: concept gap
Drop in air: 1 surface → ΔP = 2T/r. Soap bubble: 2 surfaces (inner + outer) → ΔP = 4T/r. Air bubble inside liquid: 1 surface → 2T/r.
Root cause: formula misuse
v_t ∝ r² (because Stokes drag ∝ r v, gravity ∝ r³ - r³ = r³_diff). Doubling radius quadruples terminal velocity, not doubles.
Root cause: formula misuse
Y for longitudinal stretch (FL/A·ΔL); K for volumetric compression (-V·dP/dV); G for shear. Match modulus type to deformation type before computing.
If a soap bubble expands, the pressure inside the bubble
forgets height term
Drops rho*g*h term
equates pressures incorrectly
Picks wrong reference points
ignores mass difference
Compares only specific heats, not masses
uses 2T r instead of 4T r for bubble
Treats soap bubble like a drop
expects linear acceleration
Default to constant acceleration without recognising drag-induced terminal v
uses bulk modulus formula
Confuses Y with K
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