Isothermal Adiabatic Processes

8 MCQs3 revision cards9-step worked example
Source: NCERT ThermodynamicsPYQ coverage: NEET 2022, 2023, 2024, 2025Official key: NTA-verifiedLast reviewed: May 2026

Lesson

The trap: On a P–V diagram, which curve is steeper — isothermal or adiabatic? Students routinely swap them. The adiabatic curve is always steeper than the isothermal at the same point. The slope ratio is γ (the adiabatic index, Cₚ/Cᵥ). This single confusion costs marks in graph-interpretation MCQs that appear roughly every 2–3 years.

Isothermal process. Temperature stays constant. For an ideal gas, PV = constant. All the heat supplied converts into work (ΔU = 0 because temperature doesn't change). Work done by the gas during isothermal expansion: W = nRT ln(V_f / V_i) (NCERT Class 11 Physics, Chapter 11, page 6). The process requires the system to exchange heat with a reservoir slowly enough to maintain thermal equilibrium — quasi-static by definition.

Adiabatic process. No heat exchange: Q = 0. The gas does work at the expense of its internal energy, so temperature changes. The governing relations are PVᵞ = constant and TVᵞ⁻¹ = constant (NCERT Class 11 Physics, Chapter 11, page 7). During adiabatic expansion the gas cools; during adiabatic compression it heats up.

Why the adiabat is steeper. Differentiate PV = const → dP/dV = −P/V. Differentiate PVᵞ = const → dP/dV = −γP/V. Since γ > 1 for all ideal gases, the adiabatic slope magnitude is γ times the isothermal slope at the same (P, V) point. Memorise: "adiabatic angles down sharper."

Watch-out for NEET: When a P–V diagram shows two curves through the same initial state, the steeper one is adiabatic. If the question asks which process does more work between the same initial and final volumes, compare the areas — the isothermal curve lies above the adiabat during expansion, so isothermal work > adiabatic work for the same volume change.


Practice MCQs

Select an option to see the explanation. Wrong answers show why your choice was tempting — and name the exact trap it exploits.

MCQ 1Easy RecallPractice

In an isothermal process involving an ideal gas, which quantity remains constant?

MCQ 2Easy RecallPractice

In an adiabatic process, which of the following is true?

MCQ 3Easy RecallPractice

Which equation governs an isothermal process for an ideal gas?

MCQ 4Direct ApplicationPractice

Two moles of an ideal gas expand isothermally at 300 K from volume V to 2V. The work done by the gas is:

MCQ 5Direct ApplicationPractice

On a P–V diagram, an isothermal and an adiabatic curve pass through the same point. At that point, the ratio of the magnitude of the adiabatic slope to the isothermal slope is:

MCQ 6Direct ApplicationPractice

An ideal gas undergoes adiabatic expansion. Which of the following correctly describes the changes in temperature and internal energy?

MCQ 7Concept TrapPractice

An ideal gas is compressed from volume V₁ to V₂ (V₂ < V₁) first isothermally and then adiabatically. In which process is the magnitude of work done by the gas greater?

MCQ 8Direct ApplicationPractice

During isothermal expansion of an ideal gas, the heat absorbed by the gas is:

Quick recall before you leave

Worked Example

  1. 1

    Given

    - Initial state: (P₀, V₀) for both processes - Final volume: 2V₀ - Curve A: PV = constant - Curve B: PVᵞ = constant, γ = 1.4

  2. 2

    Required

    (a) Identify which curve is isothermal and which is adiabatic. (b) Determine which process has greater work done by the gas.

  3. 3

    Concept

    Isothermal: PV = constant (Boyle's law at constant T). Adiabatic: PVᵞ = constant (no heat exchange). The adiabatic curve is steeper — its slope magnitude is γ times the isothermal slope at any common (P, V) point. During expansion to the same final volume, the isothermal curve lies above the adiabat, enclosing more area.

  4. 4

    Formula

    Isothermal work: W_iso = nRT ln(V_f / V_i) Adiabatic: PVᵞ = constant governs the curve shape.

  5. 5

    Substitution

    Both curves start at (P₀, V₀) and end at volume 2V₀. For the isothermal curve, final pressure: P_f = P₀V₀ / (2V₀) = P₀/2. For the adiabatic curve, final pressure: P_f = P₀(V₀/2V₀)ᵞ = P₀ / 2^1.4 = P₀ / 2.639.

  6. 6

    Calculation

    Since P₀/2 > P₀/2.639, the isothermal curve has a higher final pressure than the adiabatic curve at the same volume 2V₀. This means the isothermal curve lies above the adiabat throughout the expansion. The area under the P–V curve (which equals the work done) is larger for the isothermal process. Note: γ = 1.4 is exact (given in the problem). The value 2^1.4 ≈ 2.639 uses the exact exponent; the decimal is for comparison purposes.

  7. 7

    Final answer

    (a) Curve A (PV = constant) is the isothermal process; Curve B (PVᵞ = constant) is the adiabatic process. (b) The gas does more work during the isothermal expansion (larger area under the P–V curve).

  8. 8

    Common trap

    Swapping which curve is steeper. The adiabat drops more steeply because its slope is −γP/V compared to −P/V for the isotherm. Students who think the adiabat is flatter will incorrectly conclude adiabatic work > isothermal work for expansion.

  9. 9

    Similar NEET-style question

    "An ideal monoatomic gas (γ = 5/3) expands from state (P₁, V₁) to volume 3V₁ via (i) an isothermal process and (ii) an adiabatic process. In which case is the final pressure higher? In which case does the gas do more work?" (Answer: isothermal final pressure is higher; isothermal work is greater.) ---

Before solving, remember these

Process at constant temperature. For ideal gas: ΔU = 0, so Q = W. Work done: W = nRT ln(V_f/V_i).

-- NCERT, p. 6

Process with no heat exchange (Q = 0). For ideal gas: PV^γ = constant, where γ = C_p/C_v. Also TV^(γ-1) = const and TP^((1-γ)/γ) = const. ΔU = -W; system cools when expanding adiabatically.

-- NCERT, p. 7

Formulas

4 formulas — click to collapse

Adiabatic relations for ideal gas

Relations holding during reversible adiabatic process. gamma = Cp/Cv.

SymbolQuantitySI Unit
PpressurePa
Vvolumem^3
TtemperatureK
gammaadiabatic index-

Valid when

  • Q = 0 (no heat exchange)
  • Quasi-static (reversible)
  • Ideal gas

First law of thermodynamics

Change in internal energy = heat ADDED minus work DONE BY the system. Energy conservation including thermal energy.

SymbolQuantitySI Unit
Delta_Uchange in internal energyJ
Qheat added to systemJ
Wwork done BY systemJ

Valid when

  • Closed system (no mass exchange)
  • Sign convention: Q>0 heat in, W>0 system does work

Work done in isothermal process (ideal gas)

Work done by ideal gas during isothermal expansion. Q = W (since Delta_U = 0). Reverse for compression.

SymbolQuantitySI Unit
nmolesmol
Rgas constant 8.314J/mol/K
TtemperatureK
V_i, V_finitial/final volumem^3

Valid when

  • Ideal gas
  • Quasi-static (reversible) isothermal

Mayer's relation (Cp - Cv = R)

For ideal gas: difference of molar specific heats equals gas constant R. Useful for converting between Cp and Cv.

SymbolQuantitySI Unit
Cpmolar specific heat at const PJ/mol/K
Cvmolar specific heat at const VJ/mol/K
R8.314J/mol/K

Valid when

  • Ideal gas
  • Per mole basis

Exam Traps & Common Mistakes

These are the exact patterns that cause wrong answers in NEET. Each trap includes when it triggers and how to avoid it.

2 items — click to collapse

Category: Graph Interpretation

Student misidentifies which P-V curve is adiabatic (steeper) vs isothermal.

When it triggers

P-V graph showing one or more processes; question asks for process type.

How to avoid

Adiabatic curve is STEEPER than isothermal at the same point (slope ratio = γ). Adiabat: PV^γ; isotherm: PV = const.

How NEET usually asks this

2 recurring patterns from past papers — click to collapse

Sources

NCERT refs: Class 11 Physics Chapter 11, p.6 | Class 11 Physics Chapter 11, p.7

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