Isothermal process
Process at constant temperature. For ideal gas: ΔU = 0, so Q = W. Work done: W = nRT ln(V_f/V_i).
-- NCERT, p. 6The trap: On a P–V diagram, which curve is steeper — isothermal or adiabatic? Students routinely swap them. The adiabatic curve is always steeper than the isothermal at the same point. The slope ratio is γ (the adiabatic index, Cₚ/Cᵥ). This single confusion costs marks in graph-interpretation MCQs that appear roughly every 2–3 years.
Isothermal process. Temperature stays constant. For an ideal gas, PV = constant. All the heat supplied converts into work (ΔU = 0 because temperature doesn't change). Work done by the gas during isothermal expansion: W = nRT ln(V_f / V_i) (NCERT Class 11 Physics, Chapter 11, page 6). The process requires the system to exchange heat with a reservoir slowly enough to maintain thermal equilibrium — quasi-static by definition.
Adiabatic process. No heat exchange: Q = 0. The gas does work at the expense of its internal energy, so temperature changes. The governing relations are PVᵞ = constant and TVᵞ⁻¹ = constant (NCERT Class 11 Physics, Chapter 11, page 7). During adiabatic expansion the gas cools; during adiabatic compression it heats up.
Why the adiabat is steeper. Differentiate PV = const → dP/dV = −P/V. Differentiate PVᵞ = const → dP/dV = −γP/V. Since γ > 1 for all ideal gases, the adiabatic slope magnitude is γ times the isothermal slope at the same (P, V) point. Memorise: "adiabatic angles down sharper."
Watch-out for NEET: When a P–V diagram shows two curves through the same initial state, the steeper one is adiabatic. If the question asks which process does more work between the same initial and final volumes, compare the areas — the isothermal curve lies above the adiabat during expansion, so isothermal work > adiabatic work for the same volume change.
Select an option to see the explanation. Wrong answers show why your choice was tempting — and name the exact trap it exploits.
In an isothermal process involving an ideal gas, which quantity remains constant?
In an adiabatic process, which of the following is true?
Which equation governs an isothermal process for an ideal gas?
Two moles of an ideal gas expand isothermally at 300 K from volume V to 2V. The work done by the gas is:
On a P–V diagram, an isothermal and an adiabatic curve pass through the same point. At that point, the ratio of the magnitude of the adiabatic slope to the isothermal slope is:
An ideal gas undergoes adiabatic expansion. Which of the following correctly describes the changes in temperature and internal energy?
An ideal gas is compressed from volume V₁ to V₂ (V₂ < V₁) first isothermally and then adiabatically. In which process is the magnitude of work done by the gas greater?
During isothermal expansion of an ideal gas, the heat absorbed by the gas is:
Given
- Initial state: (P₀, V₀) for both processes - Final volume: 2V₀ - Curve A: PV = constant - Curve B: PVᵞ = constant, γ = 1.4
Required
(a) Identify which curve is isothermal and which is adiabatic. (b) Determine which process has greater work done by the gas.
Concept
Isothermal: PV = constant (Boyle's law at constant T). Adiabatic: PVᵞ = constant (no heat exchange). The adiabatic curve is steeper — its slope magnitude is γ times the isothermal slope at any common (P, V) point. During expansion to the same final volume, the isothermal curve lies above the adiabat, enclosing more area.
Formula
Isothermal work: W_iso = nRT ln(V_f / V_i) Adiabatic: PVᵞ = constant governs the curve shape.
Substitution
Both curves start at (P₀, V₀) and end at volume 2V₀. For the isothermal curve, final pressure: P_f = P₀V₀ / (2V₀) = P₀/2. For the adiabatic curve, final pressure: P_f = P₀(V₀/2V₀)ᵞ = P₀ / 2^1.4 = P₀ / 2.639.
Calculation
Since P₀/2 > P₀/2.639, the isothermal curve has a higher final pressure than the adiabatic curve at the same volume 2V₀. This means the isothermal curve lies above the adiabat throughout the expansion. The area under the P–V curve (which equals the work done) is larger for the isothermal process. Note: γ = 1.4 is exact (given in the problem). The value 2^1.4 ≈ 2.639 uses the exact exponent; the decimal is for comparison purposes.
Final answer
(a) Curve A (PV = constant) is the isothermal process; Curve B (PVᵞ = constant) is the adiabatic process. (b) The gas does more work during the isothermal expansion (larger area under the P–V curve).
Common trap
Swapping which curve is steeper. The adiabat drops more steeply because its slope is −γP/V compared to −P/V for the isotherm. Students who think the adiabat is flatter will incorrectly conclude adiabatic work > isothermal work for expansion.
Similar NEET-style question
"An ideal monoatomic gas (γ = 5/3) expands from state (P₁, V₁) to volume 3V₁ via (i) an isothermal process and (ii) an adiabatic process. In which case is the final pressure higher? In which case does the gas do more work?" (Answer: isothermal final pressure is higher; isothermal work is greater.) ---
Process at constant temperature. For ideal gas: ΔU = 0, so Q = W. Work done: W = nRT ln(V_f/V_i).
-- NCERT, p. 6Process with no heat exchange (Q = 0). For ideal gas: PV^γ = constant, where γ = C_p/C_v. Also TV^(γ-1) = const and TP^((1-γ)/γ) = const. ΔU = -W; system cools when expanding adiabatically.
-- NCERT, p. 7Relations holding during reversible adiabatic process. gamma = Cp/Cv.
| Symbol | Quantity | SI Unit |
|---|---|---|
| P | pressure | Pa |
| V | volume | m^3 |
| T | temperature | K |
| gamma | adiabatic index | - |
Change in internal energy = heat ADDED minus work DONE BY the system. Energy conservation including thermal energy.
| Symbol | Quantity | SI Unit |
|---|---|---|
| Delta_U | change in internal energy | J |
| Q | heat added to system | J |
| W | work done BY system | J |
Work done by ideal gas during isothermal expansion. Q = W (since Delta_U = 0). Reverse for compression.
| Symbol | Quantity | SI Unit |
|---|---|---|
| n | moles | mol |
| R | gas constant 8.314 | J/mol/K |
| T | temperature | K |
| V_i, V_f | initial/final volume | m^3 |
For ideal gas: difference of molar specific heats equals gas constant R. Useful for converting between Cp and Cv.
| Symbol | Quantity | SI Unit |
|---|---|---|
| Cp | molar specific heat at const P | J/mol/K |
| Cv | molar specific heat at const V | J/mol/K |
| R | 8.314 | J/mol/K |
These are the exact patterns that cause wrong answers in NEET. Each trap includes when it triggers and how to avoid it.
Category: Graph Interpretation
Student misidentifies which P-V curve is adiabatic (steeper) vs isothermal.
P-V graph showing one or more processes; question asks for process type.
Adiabatic curve is STEEPER than isothermal at the same point (slope ratio = γ). Adiabat: PV^γ; isotherm: PV = const.
Root cause: graph misread
Adiabatic curve is STEEPER than isothermal at the same P-V point. Slope ratio at same point: adiabatic / isothermal = γ. Memorise: 'adiabatic angles down sharper'.
forgets net zero cycle
Computes only one segment's W
swaps adiabatic isothermal curves
Confuses which curve is steeper
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