Answer: B. Palmitic acid is saturated — its straight chain packs tightly, maximizing van der Waals interactions and raising the melting point — even though it has fewer carbons than arachidonic acid, whose C=C double bonds introduce kinks that prevent tight packing and lower the melting point (NCERT Class 11 Biology, Chapter 9, page 106).
Why A is wrong: Chain length alone does not determine melting point; saturation/unsaturation is the dominant factor — arachidonic acid's double bonds lower, not raise, its melting point despite having more carbons.
Why C is wrong: Melting point is governed by the degree of saturation and resulting chain packing, not merely by the carboxyl group shared by all fatty acids.
Why D is wrong: Double bonds introduce kinks that PREVENT tight packing between chains, lowering (not raising) the melting point — this reverses the actual effect.