Chemical Kinetics
7 lessons
Topic index in NCERT order
7 of 7 lessons by the NCERT chapter they teach from, in book order. The page is the first printed page of your NCERT book the lesson cites; PYQs are the past NEET questions on that topic.
Class 12 Chemistry, Chapter 3
- Rate of Reactionp. 640 PYQs
- Factors Affecting Ratep. 660 PYQs
- Order Molecularityp. 700 PYQs
- Half Lifep. 731 PYQ
- Zero First Order Kineticsp. 734 PYQs
- Arrhenius Theoryp. 785 PYQs
- Collision Theoryp. 831 PYQ
Arrhenius Theory
Collision Theory
Factors Affecting Rate
Half Life
Order Molecularity
Rate of Reaction
Zero First Order Kinetics
Past-paper questions from this unit
12 questions from NEET 2020, 2021, 2022, 2023, 2024, 2025, 2026. Answers verified against NTA official keys.
By year in our set: 2020 (2) · 2021 (1) · 2022 (1) · 2023 (2) · 2024 (2) · 2025 (2) · 2026 (2)
Lesson: Zero First Order Kinetics
Lesson: Arrhenius Theory
Lesson: Zero First Order Kinetics
Lesson: Half Life
Lesson: Arrhenius Theory
Activation energy of any chemical reaction can be calculated if one knows the value of
Lesson: Arrhenius Theory
Lesson: Arrhenius Theory
Lesson: Zero First Order Kinetics
Lesson: Arrhenius Theory
Lesson: Zero First Order Kinetics
Lesson: Collision Theory
An increase in the concentration of the reactants of a reaction leads to change in :
Exam traps and common mistakes in this unit
Lesson: Half Life
Category: Similar Terms
Zero-order t_1/2 depends on [A]_0. First-order t_1/2 INDEPENDENT of [A]_0. Student uses wrong formula.
When it triggers
Half-life question with order specified.
How to avoid
1st order: t_1/2 = 0.693/k (constant). Zero order: t_1/2 = [A]_0/(2k) (varies with initial conc). Second order: t_1/2 = 1/(k[A]_0).
Lesson: Arrhenius Theory
Root cause: sign error
Correction
ln(k2/k1) = (Ea/R) × (1/T1 - 1/T2). At higher T2, k2 > k1, so ln(k2/k1) > 0. Need 1/T1 > 1/T2.
Lesson: Half Life
Root cause: formula misuse
Correction
First order: t_1/2 = 0.693/k (constant). Zero order: t_1/2 = [A]_0/(2k) (depends on [A]_0). Second order: t_1/2 = 1/(k[A]_0).
Lesson: Half Life
Root cause: formula misuse
Correction
Zero-order: t_1/2 = [A]_0/(2k) (depends on initial conc). First-order: t_1/2 = 0.693/k (independent of [A]_0).
Lesson: Order Molecularity
Root cause: concept gap
Correction
Rate law from EXPERIMENT, not stoichiometry. Order = sum of exponents in rate = k[A]^x[B]^y. Molecularity follows mechanism.
Formulas in this unit
Lesson: Arrhenius Theory
Arrhenius equation
Temperature dependence of rate constant. Higher Ea → more T-sensitive rate.
| Symbol | Quantity | SI Unit |
|---|---|---|
| A | frequency factor | same as k |
| Ea | activation energy | J/mol |
| R | gas constant | J/mol/K |
| T | temp | K |
Valid when
- T in kelvins
- Most reactions in modest T range
Lesson: Arrhenius Theory
Arrhenius for two temperatures
Compare rate constants at two temperatures to find Ea.
| Symbol | Quantity | SI Unit |
|---|---|---|
| k1, k2 | rate constants | same units |
| T1, T2 | temperatures | K |
| Ea | activation energy | J/mol |
Valid when
- A constant across temperature range
- T in kelvins
Lesson: Half Life
First-order kinetics
Concentration decays exponentially. Half-life independent of [A]_0.
| Symbol | Quantity | SI Unit |
|---|---|---|
| [A] | conc at time t | mol/L |
| k | rate constant | 1/s |
| t | time | s |
Valid when
- First-order reaction (rate = k[A])
Lesson: Half Life
Zero-order kinetics
Concentration decays linearly. Half-life depends on initial concentration.
| Symbol | Quantity | SI Unit |
|---|---|---|
| [A]_0 | initial conc | mol/L |
| k | rate constant | mol/L/s |
| t | time | s |
Valid when
- Zero-order reaction (rate = k, no concentration dependence)
NEET question patterns in this unit
Lesson: Arrhenius Theory
Find Ea from rate-constant ratio at two temperatures using ln(k2/k1) = Ea/R · (1/T1 − 1/T2).
Common distractors
wrong sign of 1 over t
Mixes T1 and T2 in subtraction
Lesson: Half Life
First-order: t_1/2 = 0.693/k. Apply or invert to find k or remaining concentration.
Common distractors
uses zero order formula
Plugs into [A]_0/(2k) wrong-order formula
Questions about this unit
- What does Chemical Kinetics cover for NEET Chemistry?
- 7 lessons: Arrhenius Theory, Collision Theory, Factors Affecting Rate, Half Life, Order Molecularity, Rate of Reaction and Zero First Order Kinetics.
- How often has Chemical Kinetics come up in NEET past papers?
- Our set of verified past papers has 12 questions from this unit, from NEET 2020, 2021, 2022, 2023, 2024, 2025 and 2026. Each is answered against the official NTA key.
- Is the Chemical Kinetics material free?
- Yes. All 7 lessons and 56 practice questions are free, with no login needed.