Structure of Atom

11 lessons

Topic index in NCERT order

11 of 11 lessons by the NCERT chapter they teach from, in book order. The page is the first printed page of your NCERT book the lesson cites; PYQs are the past NEET questions on that topic.

Class 11 Chemistry, Chapter 2

  1. EM Radiation Photoelectricp. 301 PYQ
  2. Hydrogen Spectrump. 450 PYQs
  3. Bohr Model Hydrogenp. 463 PYQs
  4. Bohr Limitationsp. 490 PYQs
  5. Dual Nature de Brogliep. 500 PYQs
  6. Heisenberg Uncertaintyp. 500 PYQs
  7. Quantum Numbersp. 562 PYQs
  8. Orbital Shapesp. 602 PYQs
  9. Aufbau Pauli Hundp. 620 PYQs
  10. Electronic Configurationp. 621 PYQ
  11. Half Filled Full Filled Stabilityp. 640 PYQs

Past-paper questions from this unit

9 questions from NEET 2021, 2022, 2023, 2024, 2025, 2026. Answers verified against NTA official keys.

By year in our set: 2021 (2) · 2022 (2) · 2023 (1) · 2024 (2) · 2025 (1) · 2026 (1)

Lesson: Bohr Model Hydrogen

NEET 2025

Energy and radius of first Bohr orbit of He+ and Li2+ are [Given RH = 2.18 × 10⁻¹⁸ J, a0 = 52.9 pm]

1En(Li 2+) = –8.72 × 10⁻¹⁶ J; rn(Li2+) = 17.6 pm En(He+ ) = –19.62 × 10⁻¹⁶ J; rn(He+ ) = 17.6 pm
2En(Li 2+) = –19.62 × 10⁻¹⁸ J; rn(Li2+) = 17.6 pm En(He+ ) = –8.72 × 10⁻¹⁸ J; rn(He+ ) = 26.4 pm
3En(Li 2+) = –8.72 × 10⁻¹⁸ J; rn(Li2+) = 26.4 pm En(He+ ) = –19.62 × 10⁻¹⁸ J; rn(He+ ) = 17.6 pm
4En(Li 2+) = –19.62 × 10⁻¹⁶ J; rn(Li2+) = 17.6 pm En(He+ ) = –8.72 × 10⁻¹⁶ J; rn(He+ ) = 26.4 pm
NTA Answer: Option 2(final)

Lesson: Orbital Shapes

NEET 2022

Identify the incorrect statement from the following.

1The shapes of dxy, dyz and dzx orbitals are similar to each other; and − 22 xy d and 2 z d are similar to each other.
2All the five 5d orbitals are different in size when compared to the respective 4d orbitals.
3All the five 4d orbitals have shapes similar to the respective 3d orbitals.
4In an atom, all the five 3d orbitals are equal in energy in free state.
NTA Answer: Option 1(final)

Lesson: Electronic Configuration

Exam traps and common mistakes in this unit

Lesson: Bohr Model Hydrogen

Category: Similar Terms

Student forgets Z² scaling when applying Bohr formulas to He⁺ (Z=2) or Li²⁺ (Z=3).

When it triggers

Question involves hydrogen-like ion (He+, Li2+, etc.).

How to avoid

E_n = -13.6 × Z²/n² eV. r_n = (0.529/Z) × n² Å. He+: 4× more bound than H. Li²⁺: 9× more bound. Always include Z².

Lesson: Electronic Configuration

Category: Inorganic Exception

Student writes Cr as [Ar]3d⁴4s² (expected) instead of actual [Ar]3d⁵4s¹. Same for Cu: actual [Ar]3d¹⁰4s¹ (one e⁻ promoted from 4s to 3d).

When it triggers

Question asks for ground-state electronic configuration of Cr (Z=24) or Cu (Z=29).

How to avoid

Half-filled (d⁵) and fully filled (d¹⁰) configurations have extra stability from exchange energy and symmetry. Cr and Cu adopt these configurations by promoting one 4s electron.

Lesson: Bohr Model Hydrogen

Lesson: Half Filled Full Filled Stability

Formulas in this unit

Lesson: Bohr Model Hydrogen

Bohr energy (hydrogen-like)

Energy of nth orbit. Negative (bound). Ground state H: -13.6 eV.

SymbolQuantitySI Unit
E_norbit energyeV
Znuclear charge-
nprincipal-

Valid when

  • Hydrogen-like atom
  • Non-relativistic

Lesson: Bohr Model Hydrogen

Bohr radius (hydrogen-like)

Radius of nth Bohr orbit for hydrogen-like atom of nuclear charge Z.

SymbolQuantitySI Unit
nprincipal quantum number-
Znuclear charge-
r_norbit radiusÅ

Valid when

  • Hydrogen-like (one-electron) atom
  • Non-relativistic

Lesson: Dual Nature de Broglie

de Broglie wavelength

Wavelength associated with moving particle of momentum mv.

SymbolQuantitySI Unit
hPlanck 6.626e-34J*s
mmasskg
vvelocitym/s

Valid when

  • Non-relativistic

Lesson: Heisenberg Uncertainty

Heisenberg uncertainty

Position and momentum cannot both be known with arbitrary precision.

SymbolQuantitySI Unit
Δxposition uncertaintym
Δpmomentum uncertaintykg*m/s

Valid when

  • Quantum scale; meaningful only when Δx, Δp comparable to atomic dimensions

Lesson: Hydrogen Spectrum

Rydberg formula (H spectrum)

Spectral wavelengths of hydrogen-like atoms. Lyman (n1=1, UV), Balmer (n1=2, visible), Paschen (n1=3, IR).

SymbolQuantitySI Unit
lambdawavelengthm
R_HRydberg 1.097e71/m
Znuclear charge-
n1, n2integers, n2>n1-

Valid when

  • One-electron atom

NEET question patterns in this unit

Lesson: Aufbau Pauli Hund

Lesson: Bohr Model Hydrogen

Lesson: Quantum Numbers

Questions about this unit

What does Structure of Atom cover for NEET Chemistry?
11 lessons: Aufbau Pauli Hund, Bohr Limitations, Bohr Model Hydrogen, Dual Nature de Broglie, Electronic Configuration, EM Radiation Photoelectric, Half Filled Full Filled Stability, Heisenberg Uncertainty, Hydrogen Spectrum, Orbital Shapes and Quantum Numbers.
How often has Structure of Atom come up in NEET past papers?
Our set of verified past papers has 9 questions from this unit, from NEET 2021, 2022, 2023, 2024, 2025 and 2026. Each is answered against the official NTA key.
Is the Structure of Atom material free?
Yes. All 11 lessons and 88 practice questions are free, with no login needed.